3D printing – Warping and its causes

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Magigoo chemist Jean Paul Formosa, shares his insight and knowlege with regards to 3D print warping. Follow this 4 part blog series to learn how and why warping happens and how to best reduce it.

Introduction

In this 2 part series of blog posts we will be exploring

    • Warping and its causes.
    • Factors that control the warp.
    • Effects of build plate temperature and how better settings result in less warping.
    • Improving the first layer adhesion further for perfect 3D prints.

Thermoplastic materials of different material compositions achieve optimum adhesion with different adhesion products. PLA, ABS and PET-G adhere firmly to the Original Magigoo® adhesive when the build-plate is hot and are easy to remove once the build-plate cools down. In addition to the original Magigoo® adhesive which is suited for printing conventional FDM materials, the Magigoo® Pro range consists of four additional adhesives designed specifically for use with different engineering grade materials. The range includes Magigoo® PC for polycarbonate filaments, Magigoo® PA for Nylon and reinforced Nylon filaments, Magigoo® PP for polypropylene and other poly-olefinic materials and Magigoo® PPGF which is specifically tailored for glass fibre reinforced polypropylene filaments. Magigoo® products (seen in Figure 1) are designed and tested to be used on heated build-plates with glass surfaces, yet Magigoo products also work on other build surfaces such as aluminium, PEI and Kapton tape.

Figure 1: The whole Magigoo first layer 3D printing adhesives offering for ABS, PETG, HIPS, Nylon, PC, PP, Glass and Carbon infused PP, PC and Nylon filaments and others.

At Magigoo our aim is to help make your bed adhesion issues a thing of the past by suggesting the optimal settings for reliable bed adhesion each time. Unfortunately every FDM printer and its environment is different so different materials will require different printer settings for optimal adhesion.

Therefore, we have been testing many materials with different Magigoo® adhesives on the Ultimaker S5, so you don’t have to. All the best settings will be shared as a downloadable file at the end of the series. Profiles for these tested materials can also be shared with those interested (kindly send an email to [email protected] requesting these). Kindly scroll down to see this list.

What causes warping?

The FDM printing process requires that a polymer is molten and extruded onto a build-plate or a previous layer of extruded material, layer by layer. Each layer will thus be cooling at different rates leading to a temperature differential when the object is being printed. This manufacturing method will thus result in a part which is cooling non-uniformly, this leads to several issues including warping and print-failure due to insufficient adhesion.

Warping is when the print starts to lift up from the corners and deforming in a lateral direction (Figure 2). In extreme cases warping will cause the print to completely detach from the printer but even in mild cases it can be detrimental due to loss of dimensional accuracy which can lead to the part being unusable depending on the application. The severity of warp will depend on a number of factors with some materials being more prone to warp than others. It goes without saying that for a successful print this detrimental effect needs to be avoided as much as possible.

Figure 2: Nylon 3D print printed on Magigoo PA (Nylon) on the right shows no sign of warping. The left side printed on another adhesive shows warping due to insufficient bed adhesion.

The cause of warping can be attributed to the differential thermal contraction of each successive printed layer:

Figure 3: First Layer of 3D Print deposited on printing platform.

1. When the first layer is extruded onto the build-plate, it starts immediately cooling down to the build plate temperature, this will lead to the first layer to contract slightly (Figure 3).

Figure 4: Second layer of a 3d print deposited on the previous first layer.

2. The second layer will be deposited on the already contracted first layer while also cooling down, thus contracting on top of the first layer. Since the bottom layer is already slightly contracted when the upper layer is deposited, the upper layer will cause the layer below it to compress (Figure 4).

Figure 5: 3D Print warping due to thermal gradient

3. This process will keep on repeating itself as new layers are added causing more lateral compression of the lower layers. This results in an overall sheer force between the printed layers which we can call warping stress. If the warping stress is larger than the stiffness of the part and the bed adhesion the bottom of the print will inevitably start pulling away from the build plate. (Figure 5).

The amount of warp depends on several factors including the material properties and the printing conditions which are not independent of each other. One of the most important material properties governing the amount of warp in a print is the CTE (coefficient of thermal expansion). The CTE describes the tendency of a material to change its shape, area and volume as the temperature changes. A material with a high numerical value for linear CTE exhibits large changes in length as a response to temperature change. As a result materials which have a high CTE are more prone to warping than materials which do not exhibit large changes in dimensions during the thermal changes present during FDM printing.

In addition to CTE, change in the crystallinity of the material during cooling need to be consider. Crystalline materials such as PP and PEEK will crystallise on cooling from the molten state. Crystallisation can lead to potentially higher shrinkage rates since crystalline structures tend to be more tightly packed. The crystallisation of a material depends on several factors and merits a
discussion of its own, at this point it is sufficient to assume that crystalline materials such as PP, some nylons and PEEK tend to warp more than amorphous plastics.

In the next part of this series we will go into further details on how to prevent this warping effect. Make sure not to miss it. In the mean time:

Manufacturer Material Magigoo Type 1st layer build-plate temperature (°C) Default Bed Temperature (°C) Brim (mm)
BASF Innofil3D Ultrafuse® PP GF30 PPGF 100 20 20
BASF Innofil3D PP Natural PP 80 70 20
BASF Innofil3D ASA Natural PC 110 110 No
BASF Innofil3D PET CF ABS 80 75 No
BASF Innofil3D PAHT CF15 PA 80 75 No
Clariant PA6/66 FR PA 90 80 7
Clariant PA6/66-GF20 FR PA 80 80 No
Colorfabb XT-Clear ABS 75 75 No
DOW® EVOLV3D™ OBC PP 110 100 20
DSM Arnitel® 2060 HT Flex 90 80 20
DSM Novamid® 1030CF PA 70 65 No
DSM Novamid® 1070 PA 95 85 20
DSM Arnitel® 2045 Flex 80 70 20
DSM Novamid® 1030 PA 80 80 7
DuPont™ Zytel® 3D1000FL PA 100 90 20
DuPont™ Hytrel® 3D4100FL PA 105 95 20
Fibreforce Nylforce CF PA 90 85 20
Fibreforce Nylforce GF PA 100 90 20
Filkemp Nylon PA 70 70 No
FormFutura® Centaur PP PP 80 70 20
Fiber Three F3 PA Pure Lite PA 80 80 No
Fiber Three F3 PA Pure Pro PA 80 80 No
IGUS® I180 PC 110 110 20
Lehmann Voss LUVOCOM® 3F PAHT CF 9742 BK PA 105 100 No
Lehmann Voss PAHT PA 70 70 No
Lehmann Voss LUVOCOM® 3F PAHT GK 9874 NT PA 70 70 No
Matterhackers Nylon X PA 90 80 8
Matterhackers Nylon Pro PA 70 70 7
Matterhackers Nylon G PA 90 80 8
Owens Corning X-Strand™ GF30-PP PPGF 100 20 20
Owens Corning X-Strand™ GF30-PA6 PA 75 70 No
Polymaker PolyLite™ PC PC 110 110 No
Polymaker PolyMide™ PA6-GF PA 75 75
Polymaker PolyMax™ PC PC 110 110 No
Polymaker PolyMide™ PA6-CF PA 75 70 No
Polymaker PolyMide™ CoPA PA 70 70 No
Taulman3D Bridge PA 70 60 20
Taulman3D 645 PA 70 60 20
Taulman3D 680 PA 70 60 No
Ultimaker CPE ABS 75 75 7
Ultimaker TPU95A ABS 0 0 8.75
Ultimaker PC PC 105 105 No
Ultimaker Nylon PA 90 80 No
Ultimaker PP PP 80 70 20
Ultimaker ABS ABS 85 85 7
Verbatim PP PPGF 80 70 20

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